Sorry the layout is lame, I did something simple xD I will update this as people ask questions!
Please feel free to ask me tips & tricks and other things, but don't ask me how to work a program.
FINISHED PIECE: Does it mater what order the layers are for shading and stuff?You can experiment. Depending on the effect it can com out differently. Since my lighting layer is above the shading layer, it pops more. If I had the shading layer above the lighting layer, the shading would come out too dark. It all depends on the program and the effects, so experiment.
Here are my layers:
* Extra lighting
* Lighting (luminosity)
* Shading (multiply)
* Overlay (the pink hue)
Flat Color Layer
The bolded ones above are stand alone, the ones with the * are clipped onto the flatcolor layer.